1-Allyl-3-benzyl-1H-benzimidazol-2(3H)-one

Acta Crystallogr Sect E Struct Rep Online. 2013 Aug 31;69(Pt 9):o1477-8. doi: 10.1107/S1600536813023568. eCollection 2013.

Abstract

In the title compound, C17H16N2O, the fused benzimidazol-2(3H)-one system is essentially planar, the largest deviation from the mean plane being 0.006 (2) Å for the carbonyl C atom. Its mean plane is almost perpendicular to the benzyl plane and to the allyl group, making dihedral angles of 80.6 (1) and 77.4 (3)°, respectively. The benzyl group and the allyl subsituent lie on opposite sides of the fused ring system. In the crystal, mol-ecules are linked by bifurcated C-H⋯O hydrogen bonds in which the carbonyl O atom acts as accepter to two aromatic C-H groups, forming a two-dimensional network parallel to (001).