Luminescent mechanochromic porous coordination polymers

Chemistry. 2014 Jan 13;20(3):644-8. doi: 10.1002/chem.201303991.

Abstract

Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π-π interactions.

Keywords: coordination polymers; cuprophilicity; grinding; luminescence; mechanochromism.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Coordination Complexes / chemistry
  • Copper / chemistry
  • Crystallography, X-Ray
  • Luminescent Agents
  • Molecular Conformation
  • Polymers / chemistry*
  • Porosity
  • Quantum Theory

Substances

  • Coordination Complexes
  • Luminescent Agents
  • Polymers
  • Copper