Probing 27Al-13C proximities in metal-organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy

Frédérique Pourpoint; Aany Sofia Lilly Thankamony; Christophe Volkringer; Thierry Loiseau; Julien Trébosc; Fabien Aussenac; Diego Carnevale; Geoffrey Bodenhausen; Hervé Vezin; Olivier Lafon; Jean-Paul Amoureux

doi:10.1039/c3cc47208f

Probing 27Al-13C proximities in metal-organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy

Chem Commun (Camb). 2014 Jan 28;50(8):933-5. doi: 10.1039/c3cc47208f.

Authors

Frédérique Pourpoint¹, Aany Sofia Lilly Thankamony, Christophe Volkringer, Thierry Loiseau, Julien Trébosc, Fabien Aussenac, Diego Carnevale, Geoffrey Bodenhausen, Hervé Vezin, Olivier Lafon, Jean-Paul Amoureux

Affiliation

¹ Université Lille Nord de France, CNRS, UMR 8181 UCCS, ENSCL, Université de Lille 1, 59652 Villeneuve d'Ascq, France. frederique.pourpoint@ensc-lille.fr olivier.lafon@univ-lille1.fr.

PMID: 24301188
DOI: 10.1039/c3cc47208f

Abstract

We show how (27)Al-(13)C proximities in the microporous metal-organic framework MIL-100(Al) can be probed using advanced (27)Al-(13)C NMR methods boosted by Dynamic Nuclear Polarization.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Aluminum / chemistry
Carbon Isotopes / chemistry
Magnetic Resonance Spectroscopy*
Metals / chemistry*
Organic Chemicals / chemistry*
Porosity

Substances

Carbon Isotopes
Metals
Organic Chemicals
Aluminum