Non-point source loads of heavy metals from contaminated soil has increasingly become the major cause of heavy metal concentrations of rivers and lakes surpassed the limitation value, while only few studies had focused on quantitative monitoring of soil heavy metal transportation to water, in situ field conditions. As reported, agricultural farmland heavy metal contamination was the major contamination problem, especially for cadmium (Cd) pollution in middle and downstream of Xiangjiang River. This study selected the typical Cd polluted agricultural watershed for a case study, three typical landuse types of rice, dry farmland and unused grassland with three replicate quadrates were carried out for natural rainfall runoff hydrology processes monitoring, from 2011-2012. Results showed that, precipitation pH value increased from spring to summer, soluble Cd concentration of spring runoff was significantly higher than that of summer rainfall runoff, which presented an obviously seasonal heterogeneity and had a negative correlation with rainfall pH value, and rainfall pH value can obviously impact soil soluble Cd transportation into surface runoff charge. In the same rainfall event, soluble Cd concentration and non-point load of rice were significantly lower than those of dry land and unused grassland, while no obviously seasonal trend was found for non-point load of Cd from three typical landuse types because of the rainfall depth variance, which needs more researches and concerns in the future. These results can provide valuable data and scientific supports for watershed scale's heavy metal non-point source load quantitative estimation and water environment management and water quality diagnosis and early warning.