Effective slippage on superhydrophobic trapezoidal grooves

J Chem Phys. 2013 Nov 7;139(17):174708. doi: 10.1063/1.4827867.

Abstract

We study the effective slippage on superhydrophobic grooves with trapezoidal cross-sections of various geometries (including the limiting cases of triangles and rectangular stripes), by using two complementary approaches. First, dissipative particle dynamics (DPD) simulations of a flow past such surfaces have been performed to validate an expression [E. S. Asmolov and O. I. Vinogradova, J. Fluid Mech. 706, 108 (2012)] that relates the eigenvalues of the effective slip-length tensor for one-dimensional textures. Second, we propose theoretical estimates for the effective slip length and calculate it numerically by solving the Stokes equation based on a collocation method. The comparison between the two approaches shows that they are in excellent agreement. Our results demonstrate that the effective slippage depends strongly on the area-averaged slip, the amplitude of the roughness, and on the fraction of solid in contact with the liquid. To interpret these results, we analyze flow singularities near slipping heterogeneities, and demonstrate that they inhibit the effective slip and enhance the anisotropy of the flow. Finally, we propose some guidelines to design optimal one-dimensional superhydrophobic surfaces, motivated by potential applications in microfluidics.