The Kramers-Kronig relations for usual and anomalous Poisson-Nernst-Planck models

J Phys Condens Matter. 2013 Nov 20;25(46):465104. doi: 10.1088/0953-8984/25/46/465104. Epub 2013 Oct 17.

Abstract

The consistency of the frequency response predicted by a class of electrochemical impedance expressions is analytically checked by invoking the Kramers-Kronig (KK) relations. These expressions are obtained in the context of Poisson-Nernst-Planck usual or anomalous diffusional models that satisfy Poisson's equation in a finite length situation. The theoretical results, besides being successful in interpreting experimental data, are also shown to obey the KK relations when these relations are modified accordingly.

Publication types

  • Research Support, Non-U.S. Gov't