Understanding TiO(2) size-dependent electron transport properties of a graphene-TiO(2) photoanode in dye-sensitized solar cells using conducting atomic force microscopy

Adv Mater. 2013 Dec 17;25(47):6900-4. doi: 10.1002/adma.201303327. Epub 2013 Oct 1.

Abstract

Conducting AFM reveals a continuous conduction network of a TiO2 -graphene composite in DSSC due to a more intimate contact between the smaller sized TiO2 -graphene composite nanosheets,which reduces the internal resistance at TiO2 /TiO2 and TiO2 /FTO interfaces and ultimately leads to a faster and more efficient electron transport in the photoanode.

Keywords: conducting atomic force microscopy; dye-sensitized solar cell; graphene-TiO2; nanoscale electronic properties; size-dependent charge transport.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Coloring Agents / chemistry*
  • Electric Power Supplies
  • Electrodes
  • Electron Transport
  • Graphite / chemistry*
  • Microscopy, Atomic Force
  • Nanostructures / chemistry
  • Particle Size
  • Solar Energy*
  • Titanium / chemistry*

Substances

  • Coloring Agents
  • titanium dioxide
  • Graphite
  • Titanium