Tetra-ethyl-ammonium dicyanido(5,10,15,20-tetra-phenyl-porphyrinato)ferrate(III) di-chloro-methane monosolvate

Nazira Kassenova; Oleksandr Hietsoi; Rakhmetulla Yerkassov; Michael Shatruk

doi:10.1107/S1600536813019119

Tetra-ethyl-ammonium dicyanido(5,10,15,20-tetra-phenyl-porphyrinato)ferrate(III) di-chloro-methane monosolvate

Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 17;69(Pt 8):m462-3. doi: 10.1107/S1600536813019119. eCollection 2013.

Authors

Nazira Kassenova¹, Oleksandr Hietsoi, Rakhmetulla Yerkassov, Michael Shatruk

Affiliation

¹ Department of Chemistry, L.N. Gumilyov Eurasian National University, 5 Munaitpasov Str, 010008 Astana, Kazakhstan.

Abstract

The title compound, (C8H20N)[Fe(C44H28N4)(CN)2]·CH2Cl2 or (Et4N)[Fe(TPP)(CN)2], was recrystallized from di-chloro-methane-diethyl ether. The compound crystallizes with the two unique halves of the Fe(III) porphyrinato complex, one tetra-ethyl-ammonium cation and one inter-stitial di-chloro-methane mol-ecule within the asymmetric unit. Both anionic Fe(III) complexes exhibit inversion symmetry. Both the cation and the solvent mol-ecules show positional disorder. The cation is disordered over two sets of sites with an occupancy ratio of 0.710 (3):0.290 (3); the solvent mol-ecule is disordered over three positions with a 0.584 (6):0.208 (3):0.202 (5) ratio. The crystal packing features columns of [Fe(TPP)(CN)2](-) anions that propagate along [001]. The columns further pack into layers that are parallel to (011) and also include the Et4N(+) cations. The inter-stitial CH2Cl2 mol-ecules appear in the inter-layer space. This complex may serve as a useful precursor for the assembly of multinuclear and extended CN-bridged complexes for the design of single-mol-ecule and single-chain magnets, respectively.