Dichloridobis[3-(4-chloro-phen-yl)-2,N,N-trimethyl-2,3-di-hydro-1,2,4-oxa-diazole-5-amine-κN (4)]platinum(II)-4-chloro-benzaldehyde (1/1)

Andreii S Kritchenkov; Vladislav V Gurzhiy; Nadezhda A Bokach; Valentina A Kalibabchuk

doi:10.1107/S1600536813017376

Dichloridobis[3-(4-chloro-phen-yl)-2,N,N-trimethyl-2,3-di-hydro-1,2,4-oxa-diazole-5-amine-κN (4)]platinum(II)-4-chloro-benzaldehyde (1/1)

Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 10;69(Pt 8):m446-7. doi: 10.1107/S1600536813017376. eCollection 2013.

Authors

Andreii S Kritchenkov¹, Vladislav V Gurzhiy, Nadezhda A Bokach, Valentina A Kalibabchuk

Affiliation

¹ Department of Chemistry, Saint Petersburg State University, Universitetsky Pr. 26, 198504 Stary Petergof, Russian Federation.

Abstract

In the title 1:1 co-crystal, [PtCl2(C11H14ClN3O)2]·C7H5ClO, the coordination polyhedron of the Pt(II) atom is slightly distorted square-planar with the chloride and 2,3-di-hydro-1,2,4-oxa-diazole ligands mutually trans, as the Pt atom lies on an inversion center. The 4-chloro-benzaldehyde mol-ecules are statistically disordered about an inversion centre with equal occupancies for the two positions. The Pt(II) complex forms a three-dimensional structure through C-H⋯Cl and weaker C-H⋯O inter-actions with the 4-chloro-benzaldehyde mol-ecule.