Abstract
A triarylphosphine reagent that reacts with organic azides to install amide-linked diazirines is reported. This traceless Staudinger reagent reacts with complex organic azides to yield amide-linked diazirines, thus expanding the scope of the utility of both azide and diazirine chemistry.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Azides / chemistry*
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Diazomethane / chemistry*
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Indicators and Reagents / chemistry*
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Molecular Structure
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Phosphines / chemistry*
Substances
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Azides
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Indicators and Reagents
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Phosphines
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Diazomethane