Steric hindrance-enforced distortion as a general strategy for the design of fluorescence "turn-on" cyanide probes

Bin Chen; Yubin Ding; Xin Li; Weihong Zhu; Jonathan P Hill; Katsuhiko Ariga; Yongshu Xie

doi:10.1039/c3cc46008h

Steric hindrance-enforced distortion as a general strategy for the design of fluorescence "turn-on" cyanide probes

Chem Commun (Camb). 2013 Oct 3;49(86):10136-8. doi: 10.1039/c3cc46008h.

Authors

Bin Chen¹, Yubin Ding, Xin Li, Weihong Zhu, Jonathan P Hill, Katsuhiko Ariga, Yongshu Xie

Affiliation

¹ Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, P. R. China. yshxie@ecust.edu.cn.

PMID: 24048509
DOI: 10.1039/c3cc46008h

Abstract

For the rational design of fluorescence "turn-on" cyanide probes, a general strategy is developed by introducing a dicyanovinyl group at the sterically demanding position of a large π framework.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Anions
Crystallography, X-Ray
Cyanides / chemistry*
Fluorescent Dyes / chemistry*
Molecular Structure
Nitriles / chemistry
Quantum Theory*
Quinolizines / chemistry
Time Factors

Substances

Anions
Cyanides
Fluorescent Dyes
Nitriles
Quinolizines
9-(dicyanovinyl)julolidine