Abstract
The CF3SO3H-promoted ring opening of gem-difluorocyclopropyl ketones prefers to undergo proximal bond cleavage and the subsequent cyclization with nitriles occurred smoothly to give 2-fluoropyrroles.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Crystallography, X-Ray
-
Hydrocarbons, Fluorinated / chemistry*
-
Ketones / chemistry*
-
Models, Molecular
-
Molecular Structure
-
Nitriles / chemistry*
-
Pyrroles / chemical synthesis*
-
Pyrroles / chemistry
Substances
-
Hydrocarbons, Fluorinated
-
Ketones
-
Nitriles
-
Pyrroles