Carbon-coated Li3 N nanofibers for advanced hydrogen storage

Adv Mater. 2013 Nov 20;25(43):6238-44. doi: 10.1002/adma.201301927. Epub 2013 Aug 21.

Abstract

3D porous carbon-coated Li3 N nanofibers are successfully fabricated via the electrospinning technique. The as-prepared nanofibers exhibit a highly improved hydrogen-sorption performance in terms of both thermodynamics and kinetics. More interestingly, a stable regeneration can be achieved due to the unique structure of the nanofibers, over 10 cycles of H2 sorption at a temperature as low as 250 °C.

Keywords: electrospinning; hydrogen storage; lithium nitride; nanofiber; porous.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Carbon / chemistry*
  • Hydrogen / chemistry*
  • Kinetics
  • Lithium Compounds / chemistry*
  • Nanofibers / chemistry*
  • Nitrogen Compounds / chemistry*
  • Polyvinyl Alcohol / chemistry
  • Porosity
  • Thermodynamics

Substances

  • Lithium Compounds
  • Nitrogen Compounds
  • Carbon
  • Hydrogen
  • Polyvinyl Alcohol