Abstract
A chiral porous metal-organic framework of an axially C2-symmetric 1,1'-biphenol ligand is constructed and can be used as a solid-state host to enanioselectively adsorb mandelates with up to 93.1% ee and to entrap achiral tropolone ethers and induce their asymmetric photocyclization with up to 98.5% ee.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Adsorption
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Cyclization
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Ethers / chemistry*
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Mandelic Acids / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemistry*
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Particle Size
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Photochemical Processes
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Porosity
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Stereoisomerism
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Surface Properties
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Tropolone / chemistry*
Substances
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Ethers
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Mandelic Acids
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Organometallic Compounds
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Tropolone