Abstract
The unsaturated side chain of l-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligopeptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Alkynes / chemistry*
-
Amino Acid Sequence
-
Catalysis
-
Glycine / analogs & derivatives*
-
Glycine / chemistry
-
Hydrogen / chemistry
-
Hydrogenation
-
Magnetic Resonance Spectroscopy
-
Oligopeptides / chemical synthesis*
-
Oligopeptides / chemistry
-
Sulfhydryl Compounds / chemistry
Substances
-
Alkynes
-
Oligopeptides
-
Sulfhydryl Compounds
-
propargylglycine
-
Hydrogen
-
Glycine