Abstract
Microphyllandiolide (1), an unprecedented rearranged clerodane-type diterpene with a 9/3 bicyclic ring system, was isolated from the aerial parts of Salvia microphylla Kunth. Its structure was elucidated by analysis of its spectroscopic data and confirmed by single crystal X-ray diffraction analysis. A possible biogenesis for microphyllandiolide (1) is proposed.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Crystallography, X-Ray
-
Diterpenes, Clerodane / chemical synthesis*
-
Diterpenes, Clerodane / chemistry*
-
Diterpenes, Clerodane / isolation & purification
-
Magnetic Resonance Spectroscopy
-
Models, Molecular
-
Molecular Structure
-
Salvia / chemistry*
-
X-Ray Diffraction
Substances
-
Diterpenes, Clerodane
-
microphyllandiolide