1-Allyl-2-amino-pyridin-1-ium bromide

Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):o884. doi: 10.1107/S1600536813012452. Print 2013 Jun 1.

Abstract

In the cation of the title salt, C8H11N2 (+)·Br(-), the dihedral angle between the planes of the pyridinium ring and the allyl group is 79.4 (3)°. In the crystal, N-H⋯Br and weak C-H⋯Br hydrogen bonds link the cations and anions, forming chains of alternating R 2 (1)(7) and R 4 (2)(8) rings, which run parallel to the c-axis direction. The crystal studied was an inversion twin with components in a 0.753 (12):0.247 (12) ratio.