6,8-Di-bromo-3-nitro-2-phenyl-2H-chromene

Acta Crystallogr Sect E Struct Rep Online. 2013 May 11;69(Pt 6):o877. doi: 10.1107/S160053681301221X. Print 2013 Jun 1.

Abstract

In the title compound, C15H9Br2NO3, the chromene unit is not quite planar (r.m.s. deviation from planarity = 0.0888 Å). The di-hydro-pyran ring adopts an envelope conformation with the phenyl-substituted C atom fused to the di-hydro-pyran ring as the flap. The dihedral angle between the plane defined by this C atom and the adjacent C and O atoms and the mean plane of the di-hydro-pyran ring excluding the phenyl-substituted C atom is 25.1 (3)°. The dihedral angle between the mean plane of the chromene unit and the phenyl ring is 85.7 (1)°. The crystal structure features C-H⋯O hydrogen bonds and Br⋯O contacts [3.289 (3) Å] involving the nitro O atoms.