catena-Poly[[(tri-phenyl-phosphane-κP)silver(I)]-μ-4,4'-bi-pyridine-κ(2) N:N'-[(tri-phenyl-phosphane-κP)silver(I)]-di-μ-chlorido]

Xiao-Ming Song; Feng Hu; Hua-Tian Shi; Qun Chen; Qian-Feng Zhang

doi:10.1107/S160053681301413X

catena-Poly[[(tri-phenyl-phosphane-κP)silver(I)]-μ-4,4'-bi-pyridine-κ(2) N:N'-[(tri-phenyl-phosphane-κP)silver(I)]-di-μ-chlorido]

Acta Crystallogr Sect E Struct Rep Online. 2013 May 25;69(Pt 6):m342. doi: 10.1107/S160053681301413X. Print 2013 Jun 1.

Authors

Xiao-Ming Song¹, Feng Hu, Hua-Tian Shi, Qun Chen, Qian-Feng Zhang

Affiliation

¹ Department of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China.

Abstract

In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2] n , the Ag(I) cation is coordinated by a 4,4'-bi-pyridine N atom, a tri-phenyl-phosphane P atom and two Cl(-) anions in a distorted tetra-hedral geometry. The 4,4-bi-pyridine and Cl(-) anions bridge the Ag(I) cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H⋯Cl inter-actions link the polymeric chains into a three-dimensiona supra-molecular architecture.