(O-Methyl di-thio-carbonato-κS)tri-phenyl-tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2013 May 15;69(Pt 6):m316. doi: 10.1107/S1600536813012300. Print 2013 Jun 1.

Abstract

In the title compound, [Sn(C6H5)3(C2H3OS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).