Abstract
Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 ± 1°, they are among the most water-repellent MOFs ever reported.
Publication types
-
Research Support, Non-U.S. Gov't
-
Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
-
Copper / chemistry*
-
Hydrophobic and Hydrophilic Interactions
-
Models, Molecular
-
Molecular Structure
-
Organometallic Compounds / chemical synthesis
-
Organometallic Compounds / chemistry*
Substances
-
Organometallic Compounds
-
Copper