2-Methyl-3-(10H-pheno-thia-zin-10-yl)buta-1,3-diene-1,1,4,4-tetra-carbo-nitrile

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 5;69(Pt 5):o665. doi: 10.1107/S1600536813008799. Print 2013 May 1.

Abstract

In the title compound, C21H11N5S, the pheno-thia-zine unit has a butterfly structure, and the central six-membered ring adopts a boat conformation. The dihedral angle between the benzene rings is 127.64 (6)°, which is smaller than those reported for similar compounds because of the steric repulsion between the pheno-thia-zine and its tetra-cyano-1,3-butadiene substituent. The di-cyano-vinyl groups are almost orthogonal to one another, making a dihedral angle of 80.58 (6)°. In the crystal, the mol-ecules are aligned along the b axis. Four kinds of weak C-H⋯N inter-actions are recognized, one of which connects the mol-ecules into a one-dimensional array and the remaining three link these arrays.