New deposition technique for metal films containing inorganic fullerene-like (IF) nanoparticles

Chemphyschem. 2013 Jul 22;14(10):2125-31. doi: 10.1002/cphc.201201003. Epub 2013 May 6.

Abstract

This study describes a new method for fabrication of thin composite films using physical vapor deposition (PVD). Titanium (Ti) and hybrid films of titanium containing tungsten disulphide nanoparticles with inorganic fullerene-like structure (Ti/IF-WS2) were fabricated with a modified PVD machine. The evaporation process includes the pulsed deposition of IF-WS2 by a sprayer head. This process results in IF-WS2 nanoparticles embedded in a Ti matrix. The layers were characterized by various techniques, which confirm the composition and structure of the hybrid film. The Ti/IF-WS2 shows better wear resistance and a lower friction coefficient when compared to the Ti layer or Ti substrate. The Ti/IF films show very good antireflective properties in the visible and near-IR region. Such films may find numerous applications, for example, in the aerospace and medical technology.

Keywords: nanostructures; physical vapor deposition; thin films; titanium; tribology.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Nanoparticles / chemistry*
  • Particle Size
  • Sulfides / chemistry*
  • Surface Properties
  • Titanium / chemistry*
  • Tungsten / chemistry*
  • Volatilization

Substances

  • Sulfides
  • Titanium
  • Tungsten