Abstract
The first total synthesis of (8R,6'R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia-Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carotenoids / chemical synthesis*
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Carotenoids / chemistry
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Catalysis
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Epoxy Compounds / chemistry
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Oxidation-Reduction
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Stereoisomerism
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Xanthophylls / chemistry*
Substances
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Epoxy Compounds
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Xanthophylls
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peridinin
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Carotenoids