Fluorine NMR reporter for phosphate anions

Chem Commun (Camb). 2013 Jun 4;49(44):5070-2. doi: 10.1039/c3cc42169d. Epub 2013 Apr 25.

Abstract

A fluorine-labelled zinc(II)-dipicolylamine coordination complex reports the presence of phosphate anions in aqueous solution, especially pyrophosphate and ADP, and is used to monitor the enzymatic hydrolysis of ATP.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Adenosine Triphosphate / chemistry
  • Adenosine Triphosphate / metabolism
  • Amines / chemistry
  • Anions / chemistry
  • Coordination Complexes / chemical synthesis
  • Coordination Complexes / chemistry
  • Crystallography, X-Ray
  • Fluorine / chemistry*
  • Hydrolysis
  • Magnetic Resonance Spectroscopy*
  • Molecular Conformation
  • Phosphates / chemistry*
  • Picolinic Acids / chemistry
  • Water / chemistry
  • Zinc / chemistry

Substances

  • 2,2'-dipicolylamine
  • Amines
  • Anions
  • Coordination Complexes
  • Phosphates
  • Picolinic Acids
  • Water
  • Fluorine
  • Adenosine Triphosphate
  • Zinc