Room temperature ferromagnetism with large magnetic moment at low field in rare-earth-doped BiFeO₃ thin films

J Phys Condens Matter. 2013 May 22;25(20):206003. doi: 10.1088/0953-8984/25/20/206003. Epub 2013 Apr 25.

Abstract

Thin films of rare earth (RE)-doped BiFeO3 (where RE=Sm, Ho, Pr and Nd) were grown on LaAlO3 substrates by using the pulsed laser deposition technique. All the films show a single phase of rhombohedral structure with space group R3c. The saturated magnetization in the Ho- and Sm-doped films is much larger than the values reported in the literature, and is observed at quite a low field of 0.2 T. For Ho and Sm doping, the magnetization increases as the film becomes thinner, suggesting that the observed magnetism is mostly due to a surface effect. In the case of Nd doping, even though the thin film has a large magnetic moment, the mechanism seems to be different.

Publication types

  • Research Support, Non-U.S. Gov't