Abstract
A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods--including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies--were used to characterize this new uranyl complex.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Actinoid Series Elements / chemistry
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Coordination Complexes / chemical synthesis*
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Coordination Complexes / chemistry
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Crystallography, X-Ray
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Heterocyclic Compounds / chemistry*
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Molecular Conformation
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Oxidation-Reduction
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Phenylenediamines / chemistry*
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Quantum Theory
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Uranium / chemistry
Substances
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Actinoid Series Elements
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Coordination Complexes
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Heterocyclic Compounds
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Phenylenediamines
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salphen
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Uranium
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tetrathiafulvalene