"Giant" enhancement of the upper critical field and fluctuations above the bulk Tc in superconducting ultrathin lead nanowire arrays

ACS Nano. 2013 May 28;7(5):4187-93. doi: 10.1021/nn400604v. Epub 2013 Apr 12.

Abstract

We have produced ultrathin lead (Pb) nanowires in the 6 nm pores of SBA-15 mesoporous silica substrates by chemical vapor deposition. The nanowires form regular and dense arrays. We demonstrate that bulk Pb (a type-I superconductor below Tc = 7.2 K with a critical field of 800 Oe) can be tailored by nanostructuring to become a type-II superconductor with an upper critical field (Hc2) exceeding 15 T and signs of Cooper pairing 3-4 K above the bulk Tc. The material undergoes a crossover from a one-dimensional fluctuating superconducting state at high temperatures to three-dimensional long-range-ordered superconductivity in the low-temperature regime. We show with our data in an impressive way that superconductivity in elemental metals can be greatly enhanced by nanostructuring.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electric Conductivity*
  • Lead / chemistry*
  • Magnetic Phenomena
  • Nanotechnology / instrumentation*
  • Nanowires*
  • Temperature*

Substances

  • Lead