Indium(III) halide-catalyzed UV-irradiated radical coupling of iodomethylphosphorus compounds with various organostannanes

Itaru Suzuki; Kensuke Kiyokawa; Makoto Yasuda; Akio Baba

doi:10.1021/ol4005257

Indium(III) halide-catalyzed UV-irradiated radical coupling of iodomethylphosphorus compounds with various organostannanes

Org Lett. 2013 Apr 5;15(7):1728-31. doi: 10.1021/ol4005257. Epub 2013 Mar 21.

Authors

Itaru Suzuki¹, Kensuke Kiyokawa, Makoto Yasuda, Akio Baba

Affiliation

¹ Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

PMID: 23517288
DOI: 10.1021/ol4005257

Abstract

The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV irradiation in the presence of an indium(III) halide catalyst, for which a transmetalated allylic indium species was confirmed to be an active radical species.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Combinatorial Chemistry Techniques
Hydrocarbons, Iodinated / chemistry*
Indium / chemistry*
Molecular Structure
Organophosphorus Compounds / chemistry*
Organotin Compounds / chemistry*
Stereoisomerism
Ultraviolet Rays*

Substances

Hydrocarbons, Iodinated
Organophosphorus Compounds
Organotin Compounds
Indium