Epoxidation of alkenes through oxygen activation over a bifunctional CuO/Al2O3 catalyst

Chem Commun (Camb). 2013 Mar 7;49(19):1957-9. doi: 10.1039/c3cc37843h. Epub 2013 Jan 29.

Abstract

The epoxidation of alkenes was carried out over a CuO/Al(2)O(3) catalyst using cumene as an oxygen carrier, through a one-pot reaction, giving high conversion and selectivity with different substrates. Trans-β-methylstyrene gave the corresponding epoxide in 95% yield after 3 h.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Aluminum Oxide / chemistry*
  • Catalysis
  • Copper / chemistry*
  • Epoxy Compounds / chemistry*
  • Hydrolysis
  • Oxygen / chemistry*

Substances

  • Alkenes
  • Epoxy Compounds
  • Copper
  • Aluminum Oxide
  • Oxygen
  • cupric oxide