[Hydridotris(pyrazol-1-yl-κN(2))borato]bis-(methyl-amino-κN)(triphenyl-phos-phine-κP)ruthenium(II) chloride dichloro-methane solvate monohydrate

Yi-Dong Lin; Chin-Pei Chang; Quan-Sheng Huang; Yih-Hsing Lo

doi:10.1107/S1600536812042110

[Hydridotris(pyrazol-1-yl-κN(2))borato]bis-(methyl-amino-κN)(triphenyl-phos-phine-κP)ruthenium(II) chloride dichloro-methane solvate monohydrate

Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1346. doi: 10.1107/S1600536812042110. Epub 2012 Oct 13.

Authors

Yi-Dong Lin¹, Chin-Pei Chang, Quan-Sheng Huang, Yih-Hsing Lo

Affiliation

¹ Department of Applied Physics and Chemistry, Taipei Municipal University of Education, Taipei 10048, Taiwan.

Abstract

The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa-hedral geometry; one of the Ru-N(Tp) bonds [2.135 (8) Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N-H⋯Cl and O-H⋯Cl hydrogen bonding leads to the formation of layers parallel to (100).