Poly[(μ-1,3-thio-cyanato-κN,S)(iso-nicotin-ato-κN,O)(ethanol-κO)cadmium(II)]

Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1338. doi: 10.1107/S1600536812040913. Epub 2012 Oct 6.

Abstract

In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol-ecule and two μ-1,3-bridging thio-cyanate anions in a distorted octa-hedral N(2)O(3)S geometry. The metal cations are μ-1,3-bridged via thio-cyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O-H⋯O hydrogen bonds.