Large physisorption strain and edge modification of Pd on monolayer graphene

Nanoscale. 2013 Jan 7;5(1):124-7. doi: 10.1039/c2nr32852f. Epub 2012 Nov 12.

Abstract

Using Raman spectroscopic studies, we firstly report that Pd film deposition can induce a tensile strain at the interface between Pd and n-layer graphenes, which results in the splitting of the G peak and a red Raman shift of the 2D peak in monolayer graphene, and red Raman shifts of G and 2D peaks for other n-layer graphenes. In particular, this kind of tensile strain can be used as an effective way for edge modification or strain engineering in monolayer graphene.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorption
  • Crystallization / methods
  • Elastic Modulus
  • Graphite / chemistry*
  • Materials Testing
  • Membranes, Artificial*
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Palladium / chemistry*
  • Particle Size
  • Stress, Mechanical
  • Surface Properties
  • Tensile Strength

Substances

  • Membranes, Artificial
  • Palladium
  • Graphite