Dichlorido{2-[(3,5-diphenyl-1H-pyrazol-1-yl-κN2)methyl]pyridine-κN}palladium(II)

Acta Crystallogr C. 2012 Nov;68(Pt 11):m317-9. doi: 10.1107/S0108270112043119. Epub 2012 Oct 27.

Abstract

The title compound, [PdCl(2)(C(21)H(17)N(3))], is a member of a sequence of Pd, Pt and Co dichloride complexes bearing polysubstituted (pyrazol-1-ylmethyl)pyridine ligands. It is shown that there is a correlation between the steric bulkiness of the bidentate (pyrazol-1-ylmethyl)pyridine ligands and the Pd-N(pyrazole) distances, i.e. the larger the ligand, the longer the bond. In contrast, no trend is observed between the steric properties of the ligand and the Pd-N(pyridine) bond lengths.

MeSH terms

  • Crystallography, X-Ray
  • Ligands
  • Models, Molecular
  • Organometallic Compounds / chemistry*
  • Palladium / chemistry*
  • Pyridines / chemistry*

Substances

  • Ligands
  • Organometallic Compounds
  • Pyridines
  • dichlorido(2-((3,5-diphenyl-1H-pyrazol-1-yl-kappaN2)methyl)pyridine-kappaN)palladium(II)
  • Palladium