Improved transfer of graphene for gated Schottky-junction, vertical, organic, field-effect transistors

ACS Nano. 2012 Oct 23;6(10):9095-102. doi: 10.1021/nn303848k. Epub 2012 Sep 28.

Abstract

An improved process for graphene transfer was used to demonstrate high performance graphene enabled vertical organic field effect transistors (G-VFETs). The process reduces disorder and eliminates the polymeric residue that typically plagues transferred films. The method also allows for purposely creating pores in the graphene of a controlled areal density. Transconductance observed in G-VFETs fabricated with a continuous (pore-free) graphene source electrode is attributed to modulation of the contact barrier height between the graphene and organic semiconductor due to a gate field induced Fermi level shift in the low density of electronic-states graphene electrode. Pores introduced in the graphene source electrode are shown to boost the G-VFET performance, which scales with the areal pore density taking advantage of both barrier height lowering and tunnel barrier thinning. Devices with areal pore densities of 20% exhibit on/off ratios and output current densities exceeding 10(6) and 200 mA/cm(2), respectively, at drain voltages below 5 V.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Equipment Design
  • Equipment Failure Analysis
  • Graphite / chemistry*
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Organic Chemicals / chemistry*
  • Transistors, Electronic*

Substances

  • Organic Chemicals
  • Graphite