Abstract
The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkanes / chemistry
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Amination
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Amines / chemistry
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Boron Compounds / chemistry*
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Hydrocarbons, Aromatic / chemistry*
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Stereoisomerism
Substances
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Alkanes
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Amines
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Boron Compounds
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Hydrocarbons, Aromatic