High resolution 11B NMR of magnesium diboride using cryogenic magic angle spinning

J Chem Phys. 2012 Sep 21;137(11):114201. doi: 10.1063/1.4751476.

Abstract

Static and magic-angle spinning (11)B nuclear magnetic resonance (NMR) data at 4.7 T and 8.5 T have been obtained under cryogenic conditions on a diluted sample of magnesium diboride powder in the normal and superconducting state. The data provide accurate information on the magnetic shift and longitudinal relaxation time down to a temperature of 8 K, with a resolution improvement over the entire temperature range. The onset of superconductivity is unaffected by the sample rotation, as revealed by a steep variation of the magnetic shift just below the critical temperature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Boron / chemistry*
  • Boron Compounds / chemistry*
  • Magnesium Compounds / chemistry*
  • Magnetic Resonance Spectroscopy / standards
  • Reference Standards
  • Temperature

Substances

  • Boron Compounds
  • Magnesium Compounds
  • magnesium boride
  • Boron