Benzyl 3-[(E)-(furan-2-yl)methyl-idene]-2-methyldithio-carbazate

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2752. doi: 10.1107/S1600536812035520. Epub 2012 Aug 23.

Abstract

In the title compound, C(14)H(14)N(2)OS(2), the furan ring exhibits rotational disorder over two orientations, with an occupancy ratio of 0.508 (7):0.492 (7). The furan and phenyl rings form dihedral angles of 8.2 (6) (major occupancy component), 14.8 (6) (minor occupancy component) and 73.65 (9)°, respectively, with the central residue (C(4)N(2)S(2)), indicating a twisted conformation for the mol-ecule. The methyl group and the thione S atom are syn and the conformation about the imine bond is E. In the crystal, C-H⋯π inter-actions involving the phenyl ring are observed.