Vibrational heating in single-molecule switches: an energy-dependent density-of-states approach

J Phys Condens Matter. 2012 Oct 3;24(39):394003. doi: 10.1088/0953-8984/24/39/394003. Epub 2012 Sep 11.

Abstract

In recent experiments, it has been shown that the switching rate of single-molecule switches can show a rather complicated dependence on the applied bias voltage. Here, we discuss a minimal model which describes the switching process in terms of inelastic scattering processes of the tunneling electron by specific molecular vibrations. One important point is the introduction of an energy-dependent electronic density of states around the Fermi energy. The influence of different model parameters on the switching rate is studied and we show that the inclusion of a variable density of states allows us to understand the non-monotonic behavior of the switching rate observed in some experiments.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hot Temperature*
  • Models, Theoretical*
  • Vibration*