Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14- anion

V S Korenev; P A Abramov; C Vicent; D A Mainichev; S Floquet; E Cadot; M N Sokolov; V P Fedin

doi:10.1039/c2dt31512b

Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14- anion

Dalton Trans. 2012 Dec 28;41(48):14484-6. doi: 10.1039/c2dt31512b.

Authors

V S Korenev¹, P A Abramov, C Vicent, D A Mainichev, S Floquet, E Cadot, M N Sokolov, V P Fedin

Affiliation

¹ Nikolaev Institute of Inorganic Chemistry SB RAS, Prospect Lavrentyeva 3, 630090 Novosibirsk, Russia. wkorenev@niic.nsc.ru

PMID: 22951583
DOI: 10.1039/c2dt31512b

Abstract

Reaction between monolacunary {BW(11)} tungstoborate and oxothiocationic building block, {Mo(2)O(2)S(2)}, results in the formation of a new polyoxothiometalate with a unique architecture in which two [H(2)BW(12)O(43)](9-) tungstoborate subunits are linked together with a hexamolybdate [Mo(V)(6)O(6)S(6)(OH)(4)(H(2)O)(2)](2+) bridge.