Abstract
A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf(2)O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry*
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Oxazoles / chemistry*
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Rhodium / chemistry*
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Thiazoles / chemistry*
Substances
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Organometallic Compounds
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Oxazoles
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Thiazoles
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Rhodium