Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

Chem Commun (Camb). 2012 Oct 7;48(77):9625-7. doi: 10.1039/c2cc35020c.

Abstract

A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf(2)O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry*
  • Oxazoles / chemistry*
  • Rhodium / chemistry*
  • Thiazoles / chemistry*

Substances

  • Organometallic Compounds
  • Oxazoles
  • Thiazoles
  • Rhodium