Effect of aging time and Al substitution on the morphology of aluminous goethite

Haibo Liu; Tianhu Chen; Ray L Frost; Dongyin Chang; Chengsong Qing; Qiaoqin Xie

doi:10.1016/j.jcis.2012.07.016

Effect of aging time and Al substitution on the morphology of aluminous goethite

J Colloid Interface Sci. 2012 Nov 1;385(1):81-6. doi: 10.1016/j.jcis.2012.07.016. Epub 2012 Jul 16.

Authors

Haibo Liu¹, Tianhu Chen, Ray L Frost, Dongyin Chang, Chengsong Qing, Qiaoqin Xie

Affiliation

¹ School of Resource and Environmental Engineering, Hefei University of Technology, Hefei, China.

PMID: 22884226
DOI: 10.1016/j.jcis.2012.07.016

Abstract

Goethite and Al-substituted goethite were synthesized from the reaction between ferric nitrate and/or aluminum nitrate and potassium hydroxide. XRF, XRD, TEM with EDS were used to characterize the chemical composition, phase and lattice parameters, and morphology of the synthesized products. The results show that d(020) decreases from 4.953 to 4.949Å and the b dimension decreases from 9.951Å to 9.906Å when the aging time increases from 6 days to 42 days for 9.09 mol% Al-substituted goethite. A sample with 9.09 mol% Al substitution in Al-substituted goethite was prepared by a rapid co-precipitation method. In the sample, 13.45 mol%, 12.31 mol% and 5.85 mol% Al substitution with a crystal size of 163, 131, and 45 nm are observed as shown in the TEM images and EDS. The crystal size of goethite is positively related to the degree of Al substitution according to the TEM images and EDS results. Thus, this methodology is proved to be effective to distinguish the morphology of goethite and Al substituted goethite.