Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks

Chem Commun (Camb). 2012 Aug 7;48(61):7592-4. doi: 10.1039/c2cc33485b. Epub 2012 Jun 25.

Abstract

The magnetothermal properties of a coordination polymer and a metal-organic framework (MOF) based on Gd(3+) ions are reported. An equally large cryogenic magnetocaloric effect (MCE) is found, irrespective of the dimensionality. This combined with their robustness makes them appealing for widespread magnetic refrigeration applications.