Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')aluminium

Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m806. doi: 10.1107/S1600536812023203. Epub 2012 May 26.

Abstract

In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment. Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å. In the crystal, mol-ecules are linked via C-H⋯Cl contacts.