Sub-meter resolution in long-distance Brillouin Optical Time Domain Analysis (BOTDA) cannot be trivially achieved due to several issues including: resolution-uncertainty trade-offs, self-phase modulation, fiber attenuation, depletion, etc. In this paper we show that combining Raman assistance, differential pulse-width pair (DPP) measurements and a novel numerical de-noising procedure, we could obtain sub-meter resolution Brillouin optical time-domain analysis over a range of 100 km. We successfully demonstrate the detection of a 0.5 meter hot-spot in the position of worst contrast along the fiber.