6-Meth-oxy-1-(4-meth-oxy-phen-yl)-1,2,3,4-tetra-hydro-9H-β-carbolin-2-ium acetate

Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1483. doi: 10.1107/S1600536812016753. Epub 2012 Apr 21.

Abstract

In the title compound, C(19)H(21)N(2)O(2) (+)·C(2)H(3)O(2) (-), the 1H-indole ring system is essentially planar [maximum deviation = 0.0257 (14) Å] and forms a dihedral angle of 87.92 (7) Å with the benzene ring attached to the tetra-hydro-pyridinium fragment. The tetra-hydro-pyridinium ring adopts a half-chair conformation. In the crystal, cations and anions are linked by inter-ionic N-H⋯O, C-H⋯O and C-H⋯N hydrogen bonds into chains along the a axis.