Preparation of α- and β-D-glucoseptanose pentaacetates

Mohan Bhadbhade; Donald C Craig; Clarence J Ng; Leon Odier; John D Stevens

doi:10.1016/j.carres.2012.03.011

Preparation of α- and β-D-glucoseptanose pentaacetates

Carbohydr Res. 2012 May 15:353:86-91. doi: 10.1016/j.carres.2012.03.011. Epub 2012 Mar 23.

Authors

Mohan Bhadbhade¹, Donald C Craig, Clarence J Ng, Leon Odier, John D Stevens

Affiliation

¹ School of Chemistry, University of New South Wales, Sydney 2052, Australia.

PMID: 22533916
DOI: 10.1016/j.carres.2012.03.011

Abstract

The α- and β-D-glucoseptanose pentaacetates have been prepared by treatment of ethyl 1-thio-β-D-glucoseptanoside tetraacetate with mercury(II) acetate in acetic acid. The solid state structure of the β-isomer has been determined by X-ray diffraction.

MeSH terms

Acetates / chemistry*
Carbohydrates / chemical synthesis*
Carbohydrates / chemistry*
Magnetic Resonance Spectroscopy
Stereoisomerism
X-Ray Diffraction

Substances

Acetates
Carbohydrates