The freestanding Sb(2)S(3) films were easily synthesized at the interface of water and toluene at room temperature, where Na(2)S and (C(2)H(5)OCS(2))(3)Sb (xanthate, O-ethyldithiocarbonate) acted as sulfur and antimony source, respectively. After 3 h of aging, the Sb(2)S(3) films with a flat surface toward organic side and rough surface toward aqueous side were assembled by sheaflike Sb(2)S(3) nanowires. The Sb(2)S(3) nanorings formed by end-to-end connection of the bundled nanowires appeared in the water layer when the reaction time reached 24 h. The Sb(2)S(3) nanorings showed higher photocatalytic activity for methyl orange degradation under visible light than the Sb(2)S(3) films owing to broader spectrum response and better aqueous dispersion.