Preparation of Surface Adsorbed and Impregnated Multi-walled Carbon Nanotube/Nylon-6 Nanofiber Composites and Investigation of their Gas Sensing Ability

Sensors (Basel). 2009;9(1):86-101. doi: 10.3390/s90100086. Epub 2009 Jan 5.

Abstract

We have prepared electrospun Nylon-6 nanofibers via electrospinning, and adsorbed multi-walled carbon nanotubes (MWCNTs) onto the surface of Nylon-6 fibers using Triton(®) X-100 to form a MWCNTs/Nylon-6 nanofiber composite. The dispersed MWCNTs have been found to be stable in hexafluoroisopropanol for several months without precipitation. A MWCNTs/Nylon-6 nanofiber composite based chemical sensor has demonstrated its responsiveness towards a wide range of solvent vapours at room temperature and only mg quantities of MWCNTs were expended. The large surface area and porous nature of the electrospun Nylon-6/MWCNT nanofibers facilitates greater analyte permeability. The experimental analysis has indicated that the dipole moment, functional group and vapour pressure of the analytes determine the magnitude of the responsiveness.

Keywords: Porosity; dispersion; electrospinning; nanofibers; one dimensional material; surface functionalization.