Abstract
Palladium(II)-catalyzed aerobic oxidative cyclization of alkenes with tethered tert-butanesulfinamides furnishes enantiopure 2,5-disubstituted pyrrolidines, originating from readily available and easily diversified starting materials. These reactions are the first reported examples of metal-catalyzed addition of sulfinamide nucleophiles to alkenes.
© 2012 American Chemical Society
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkenes / chemistry*
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Butanes / chemistry*
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Catalysis
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Cyclization
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Molecular Structure
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Oxidation-Reduction
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Pyrrolidines / chemical synthesis*
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Stereoisomerism
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Sulfonamides / chemistry*
Substances
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Alkenes
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Butanes
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Pyrrolidines
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Sulfonamides
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tert-butanesulfinamide